Is it possible to automatically populate and sort a structure?

I have a 1xA cell array called Names that contains 50 unique strings (e.g. 'Knee', 'Ankle', etc.). I also have a 1xA double array called Values that contains a single value associated with each Name.

My ultimate goal is to sort the Values list and display a table that shows each Name and Value, sorted in descending order according to Value.

From my review of the Mathworks documentation, it seems that associating each name to its value using a structure may be the best option. However, all of the examples on the structure documentation page show very simple examples where each element of the structure is manually specified. In my case, this will not be possible, because in my code the value of A can vary between runs, so manually listing out the Names when creating a structure will not work.

I have been able to sort the Values list using the sort() function (and the 'descend' option), but using this method, I lose the association between the corresponding Name value.

I have played around with trying to populate a structure using a loop, but have not had success with this method.

Is there a way to:
                   ~ 1) create a structure that pairs up each Name with its associated Value?
    and then ~ 2) sort the resulting structure in descending order according to Value?

Thanks in advance for your guidance.